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Potential energies carbonyl halides

Lever has successfully predicted Mn"/ potentials of 24 Mn-carbonyl complexes containing halide, pseudohalide, isonitrile, and phosphine co-ligands, with additivity parameters derived from the potentials of Ru "/" couples [39]. An important consideration for heteroleptic complexes is the influence of isomerism on redox thermodynamics. For Mn(CO) (CNR)6- complexes, with n = 2 or 3, the Mn"/ potentials for cis/trans and fac/mer pairs differ by as much as 0.2 V [40]. The effect arises from the different a-donor and 7r-acceptor abilities of carbonyl (CO) and isocyanide and their influence on the energy of the highest energy occupied molecular orbital (HOMO). [Pg.405]

See other pages where Potential energies carbonyl halides is mentioned: [Pg.78]    [Pg.93]    [Pg.169]    [Pg.163]    [Pg.36]    [Pg.49]    [Pg.122]    [Pg.47]    [Pg.119]    [Pg.187]   
See also in sourсe #XX -- [ Pg.759 ]



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