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Carbonyl difluoride reaction with amides

The reaction of amides with sulfur tetrafluoride or with carbonyl difluoride leads to fluorinated compounds with a nitrogen substituent at the difluoromethylene or trifluoromcthyl group and thus these reactions are not covered here. [Pg.207]

Amides having only one nitrogen substituent can react with carbonyl difluoride in three ways by iV-acylation, by cleavage, or by displacement of oxygen with fluorine [632], Reactions involving AT-acylation and oxygen displacement are illustrated by the examples given in Table 13.24. The three reaction types are all illustrated by the transformations of... [Pg.646]

REACTIONS OF CARBONYL DIFLUORIDE WITH Af-MONOSUBSTITUTED AMIDES [571,632]... [Pg.646]

CARBONYL DIFLUORIDE or CARBONYL FLUORIDE (353-50-4) CFjO Noncombustible gas. Reacts with water or steam, producing hydrogen fluoride gas and carbon dioxide. Violent reaction with strong oxidizers bases including amines, amides, and inorganic hydroxides alcohols and glycols dinitrogen tetraoxie, hexafluoroisopropylideneaminolithium ethers in the presence of metal salts. If flow... [Pg.221]

See other pages where Carbonyl difluoride reaction with amides is mentioned: [Pg.495]    [Pg.524]    [Pg.480]    [Pg.1347]    [Pg.524]    [Pg.375]   
See also in sourсe #XX -- [ Pg.6 , Pg.495 ]

See also in sourсe #XX -- [ Pg.495 ]

See also in sourсe #XX -- [ Pg.6 , Pg.495 ]

See also in sourсe #XX -- [ Pg.495 ]



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Amidating reaction

Amidation reactions

Amide Reaction

Amide carbonyl

Amide carbonyl reactions

Amides carbonylation

Carbonyl difluoride

Carbonylative amidation

Reaction with amides

Reaction with carbonyl difluoride

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