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Carbonyl clusters structural parameters

The cyclometallation of simple phenoxides can be achieved at mono- and polymetallic centres via oxidative addition pathways. The cluster carbonyl [Os3(CO)i2] initially reacts with phenol to produce the hydrido, phenoxide [Os3(/i2-H)(iU.2-OPh)(CO)ii] which on subsequent thermolysis yields the nonacarbonyl whose structural parameters are consistent with a 1,3-cyclohexadienone bonding description (Eq. 6.59).2°4... [Pg.478]

See other pages where Carbonyl clusters structural parameters is mentioned: [Pg.516]    [Pg.389]    [Pg.92]    [Pg.237]    [Pg.333]    [Pg.415]    [Pg.296]    [Pg.1008]    [Pg.130]    [Pg.161]    [Pg.92]    [Pg.173]    [Pg.117]    [Pg.208]    [Pg.147]    [Pg.139]    [Pg.336]    [Pg.300]    [Pg.323]    [Pg.199]    [Pg.1969]    [Pg.169]    [Pg.134]    [Pg.445]   
See also in sourсe #XX -- [ Pg.173 ]



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