Carbonyl and Related Compounds

J. Chatt, P. L. Paulson, and L. M. Venanzi, "Metal Carbonyls and Related Compounds," io H. Zeiss, ed., Organometallic Chemisty, ACS Monograph 147, Reiohold Pubhshiog Corp., New York, 1960. 

Thermochemical studies of organo-transition metal carbonyls and related compounds. J. A. Connor, Top. Curr. Chem., 1977, 71, 72-110 (122). 

While the Michael-addition of a,P-unsaturated carbonyl and related compounds constitutes one of the most important fundamental synthetic reactions in organic chemistry, the y-addition developed by Trost and Li of nucleophiles to 2-alkynoates catalyzed by a phosphine provides... 

Connor, J. A. Thermochemical Studies of Organo-Transition Metal Carbonyls and Related Compounds. 71, 71-110 (1977). 

Sc(OTf)3 is stable in water, and effectively activates carbonyl and related compounds as a Lewis acid in water. This is remarkable, because most Lewis acids react immediately with water rather than the substrates, and are decomposed or deactivated. It has already been found that lanthanide trifiates Ln(OTf)3 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) and yttrium trifiate Y(OTf)3 are stable in water, and can act as Lewis-acid catalysts in aqueous media.46-48 They are used catalytically in many reactions and can often be recovered and reused, because they are stable under the usual water-quenching conditions. 

Carbon-carbon bond formation using addition reactions of organometallics to carbonyl and related compounds is... 

Thermochemical Studies of Organo-Transition Metal Carbonyls and Related Compounds... 

A powerful approach to the synthesis of a,p-epoxy carbonyls and related compounds is found in the Darzens reaction (Scheme 11.18b). In this context, the groups of and Arai " have investigated the asymmetric PTC-... 

I propose to develop and apply such methods, based on ultrafast X-ray absorption spectroscopy, to study the ultrafast molecular motions of organometallics in solutions. In particular, initial studies will focus on photo-induced ligand dissociation and substitution reactions of transition metal carbonyls and related compounds in various solvent systems. 

Komatsu N, Uda M, Suzuki H (1995) Bismuth(III) halides and sulfate as highly efficient catalyst for the sulfenylation of carbonyl and related compounds. Synlett 984-986... 

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