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CARBONYL ADDITIONS, CERIUM CHLORIDE-PROMOTED

CARBONYL ADDITIONS, CERIUM(III) CHLORIDE-PROMOTED, 76, 237 Carbonyl compounds, reactions with organolithiums or Grignard reagents, 76, 228 Carboxylic acid amides, 77, 27 Cells, storage of, 76, 80 Centrifugation, 76, 78... [Pg.155]

Peterson Alkenylation. The Peterson alkenylation reaction continues to be the major use of trimethylsilylmethyllithium (1) and converts a carbonyl group to a methylene (eq 1). Some enan-tioselectivity has been seen for the addition of 1 to benzaldehyde in the presence of chiral ligands. The ketone substrates can contain functional groups that are con5)atible with the basic conditions. The use of cerium(III) chloride to promote nucleophilic addition of 1 to an enolizable carbonyl compound has continued to prove advantageous. ... [Pg.665]

See other pages where CARBONYL ADDITIONS, CERIUM CHLORIDE-PROMOTED is mentioned: [Pg.452]    [Pg.237]    [Pg.130]   
See also in sourсe #XX -- [ Pg.76 , Pg.237 ]

See also in sourсe #XX -- [ Pg.76 , Pg.237 ]



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