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Carbonates, asymmetric Baylis-Hillman allylic substitution

Baylis-Hillman carbonate is a good substrate for asymmetric allylic substitution reaction, and various nucleophiles have been involved in this transformation. As shown in Scheme 9.36, the intermediate 72 (mechanistically formed by Michael... [Pg.335]

The asymmetric allylic substitution reaction of Morita-Baylis-Hillman carbonates (226) with diphenyl phosphite in the presence of chiral multifunctional thiourea-phosphine catalyst (228) provided allylic phosphites (227) in high yields and with excellent enantioselectivities (Scheme 76). [Pg.285]

See other pages where Carbonates, asymmetric Baylis-Hillman allylic substitution is mentioned: [Pg.102]    [Pg.412]    [Pg.3]   
See also in sourсe #XX -- [ Pg.335 , Pg.336 , Pg.337 , Pg.338 , Pg.339 , Pg.340 , Pg.341 ]



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Allyl carbonate

Allyl carbonates 3£)-substituted

Allyl carbonates allylation

Allyl carbonates substitutions

Allylic carbon

Allylic substitution

Allylic substitution, Baylis-Hillman

Allylic substitution, Baylis-Hillman carbonates

Asymmetric Baylis-Hillman

Asymmetric allyl substitution

Asymmetric allylation

Asymmetric allylation, Baylis-Hillman

Asymmetric allylation, Baylis-Hillman carbonates

Asymmetric allylic substitution

Asymmetric carbon

Baylis asymmetric

Baylis-Hillman

Carbon allyl

Carbon allylation

Carbonates, asymmetric Baylis-Hillman

Hillman

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