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Carbonates, allylic, coupling metal, with ketones

Butadiene)zirconocene reacts with metal carbonyls in a similar way as with ketones. Carbon-carbon coupling between a butadiene terminus and the carbonyl carbon atom occurs readily to yield a metallacyclic product, only that generally a metallacyclic n-allyl metallocene system is obtained from the reactions with metal carbonyls.8 Sometimes, O-zirconated Fischer-type carbene complexes are readily formed in this way that cannot be easily obtained by other routes. A typical example is the... [Pg.133]

See other pages where Carbonates, allylic, coupling metal, with ketones is mentioned: [Pg.1336]    [Pg.313]    [Pg.213]    [Pg.272]    [Pg.779]    [Pg.74]    [Pg.363]    [Pg.224]    [Pg.469]    [Pg.969]    [Pg.454]    [Pg.299]    [Pg.230]    [Pg.324]    [Pg.467]    [Pg.467]    [Pg.260]    [Pg.27]    [Pg.1064]    [Pg.436]    [Pg.415]    [Pg.467]    [Pg.31]    [Pg.734]    [Pg.291]    [Pg.225]    [Pg.734]    [Pg.27]    [Pg.298]    [Pg.294]    [Pg.140]    [Pg.468]   
See also in sourсe #XX -- [ Pg.1367 ]



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1.1- allyl metals

Allyl carbonate

Allyl carbonates allylation

Allylation with ketones

Allylic carbon

Allylic coupling

Allylic metalation

Carbon allyl

Carbon allylation

Carbon coupling

Carbonates, allylic, coupling

Ketones allylation

Ketones carbons

Ketones metalation

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