Carbon-mercury bonds ozonolysis

By comparison of the n-alkylmercurial results alone, it is possible to generalize that both higher ozonation temperatures and the presence of a halogen ligand on mercury promote carbon-carbon cleavage during the ozonolysis of the carbon-mercury bond. 

Reaction Stoichiometry. The results of the stoichiometry study (see Table II) were varied but did suggest a 1 1 ozone mercurial ratio for the cleavage of a carbon-mercury bond. Several problems were evident in such a study. Since mostly only the highest oxidation states for carbon were observed in the products of partial ozonation of 1°, 2°, and 3° organomercurials, it could be assumed that ozonolysis of the C—Hg bond involved the slowest step in the total reaction sequence. Hence, some... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

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