Carbon bulk-modification

Cross-sectional modifications of a more extreme nature than skin-bursting, which nevertheless do not form crimp, have grown in importance since the early 1980s. These yield a permanent bulk increase which can be translated into bulky fabrics without the need for special care. The first commercial staple fiber of this type was Courtaulds hoUow Viloft, developed in the 1970s using a carbonate inflation technique (37). 

Biopolymers have diverse roles to play in the advancement of green nanotechnology. Nanosized derivatives of polysaccharides like starch and cellulose can be synthesized in bulk and can be used for the development of bionanocomposites. They can be promising substitutes of environment pollutant carbon black for reinforcement of rubbers even at higher loadings (upto SOphr) via commercially viable process. The combined effect of size reduction and organic modification improves filler-matrix adhesion and in turn the performance of polysaccharides. The study opens up a new and green alternative for reinforcement of rubbers. 

The oxidation of carbon monoxide on nickel oxide has often been investigated (4, 6, 8, 9, II, 16, 17, 21, 22, 26, 27, 29, 32, 33, 36) with attempts to correlate the changes in the apparent activation energy with the modification of the electronic structure of the catalyst. Published results are not in agreement (6,11,21,22,26,27,32,33). Some discrepancies would be caused by the different temperature ranges used (27). However, the preparation and the pretreatments of nickel oxide were, in many cases, different, and consequently the surface structure of the catalysts—i.e., their composition and the nature and concentration of surface defects— were probably different. Therefore, an explanation of the disagreement may be that the surface structure of the semiconducting catalyst (and not only its surface or bulk electronic properties) influences its activity. 

In specific cases, electrode bulk as opposed to surface modification can be employed, as with carbon paste electrodes23. The modifier, a substance that reacts preferentially in some way with a species to be determined, is mixed directly with the carbon paste. The mode of action is either by catalyzing the analyte reaction or pre-concentrating the analyte on the surface before determination. 

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