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Carbohydrates pyranoses

The incorporation of heteroatoms can result in stereoelectronic effects that have a pronounced effect on conformation and, ultimately, on reactivity. It is known from numerous examples in carbohydrate chemistry that pyranose sugars substituted with an electron-withdrawing group such as halogen or alkoxy at C-1 are often more stable when the substituent has an axial, rather than an equatorial, orientation. This tendency is not limited to carbohydrates but carries over to simpler ring systems such as 2-substituted tetrahydropyrans. The phenomenon is known as the anomeric ect, because it involves a substituent at the anomeric position in carbohydrate pyranose rings. Scheme 3.1 lists... [Pg.151]


See other pages where Carbohydrates pyranoses is mentioned: [Pg.1036]    [Pg.1037]    [Pg.1039]    [Pg.1036]    [Pg.1037]    [Pg.1039]    [Pg.361]    [Pg.1043]    [Pg.1044]    [Pg.1046]    [Pg.981]    [Pg.981]    [Pg.983]    [Pg.227]    [Pg.981]    [Pg.983]    [Pg.1032]    [Pg.1033]    [Pg.147]    [Pg.956]    [Pg.957]    [Pg.130]    [Pg.24]   
See also in sourсe #XX -- [ Pg.153 , Pg.158 ]




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