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Carbocationic properties

The thiazolium ring, as most heterocycloammoniums, is a Lewis acid conferring to the carbon atom in the 2-position the carbocationic property of adding the free pair of a base either organic or mineral that may be the molecule of solvent as ROH (Scheme 11). For many nuclei of suitable acidity, these equilibria can be observed in dilute solution by means of absorption spectra when species A and C possess different characteristics (24). For example, benzothiazolium and benzoxazolium in methanol and ethanol give at 10 mole liter 8 and 54% of the alkoxy derivatives for the former and 29 and 90% for the latter respectively. [Pg.32]

A large variety of salts of triflic acid formed both from metals and nonmetals are known Many of these salts are versatile reagents for organic synthesis because of such properties of the tnflate anion as very low nucleophilicity and low coordinating ability However, despite low nucleophilicity, the triflate anion can combine with carbocationic intermediates under appropriate conditions to form triflate esters [116, 117, II8. ... [Pg.964]

The pioneering work Forster and Hoffmann [28] on the viscosity dependence of the fluorescence quantum yield of triphenylmethane dyes (TPM) has set the foundation for several reports in these dyes (Fig. 12). It was found that both an ability to twist around the carbocationic center and the donor-acceptor properties are important [66], Specifically, a strong intramolecular quenching is observed for 34 that is virtually absent (two orders of magnitude slower quenching rate) in the bridged... [Pg.283]

The dissociation constant KD, which is often derived from spectral properties in carbanion chemistry, therefore includes a covalent term that corresponds to Kx in carbocationic chemistry. As one would not expect equal reactivity of benzhydryl chloride and benzhydryl cations, one also should not expect equal reactivity for benzhydryl lithium and benzhydryl anions. As one realizes that the terms contact ion-pair and dissociation have a different meaning in carbocation and carbanion chemistry, the apparent discrepancies quoted above, will disappear. [Pg.91]

The basic data related to the structure and properties of various carbocationic derivatives can be found in a treatise Olah, G. Schleyer, P. von R. Carbonium Ions, Wiley, New York, 1968-1976, vols. 1-5 for a consise review, see Bethell, G. Reactive Intermediates, Wiley, New York, 1978, vol. I. [Pg.225]

Styrene is one of the few monomers that may be polymerized by free-radical, anionic, cationic, or coordination (Ziegler-Natta) methods. This property, common to styrene and most of its derivatives, is the consequence of the availability of a benzylic position in these monomers, which is capable of stabilizing a radical, carbanionic, or carbocationic center, as well as possessing a polarizability amenable to the charge distributions required by coordination methods of polymerization. [Pg.746]

In recent years, there have been significant developments in the field of living carbocationic polymerization (LCCP) of vinyl monomers, such as isobutylene (IB), styrene and its derivatives, and vinyl ethers, leading to a wide variety of functional polymers (for recent reviews see Refs. 1-4). Due to the attractive properties of polyisobutylene (PIB) available only by carbocationic polymerization, coupling this hydrophobic, thermally, oxidatively, and hydrolytically stable polymer with a low Tg to a variety of other chain segments is expected to result in new useful products. For instance, methacrylate-telechelic PIB (MA-PIB-MA) obtained by LCCP and subsequent chain end derivatization has been successfully used to synthesize novel amphiphilic networks by radical copolymerization of MA-PIB-MA with a variety of monomers, such as N,N-dimethylacrylamide and 2-trimethylsilyloxyethyl methacrylate, a protected 2-hydroxyethyl methacrylate... [Pg.122]

A characteristic property of carbenium ions in gemral and arenium ones in particular is a shift of one of the eronns located at the sp -hybridized carbon atom to the neighbouring positively charged carbon atom (carbocationic cratie) ... [Pg.143]

Table 3. Dielectric, Electron Acceptor, and Donor Properties of Solvents Used for Carbocationic Polymerization... Table 3. Dielectric, Electron Acceptor, and Donor Properties of Solvents Used for Carbocationic Polymerization...

See other pages where Carbocationic properties is mentioned: [Pg.335]    [Pg.335]    [Pg.193]    [Pg.194]    [Pg.354]    [Pg.75]    [Pg.278]    [Pg.107]    [Pg.133]    [Pg.306]    [Pg.402]    [Pg.40]    [Pg.242]    [Pg.205]    [Pg.281]    [Pg.310]    [Pg.159]    [Pg.384]    [Pg.318]    [Pg.185]    [Pg.182]    [Pg.184]    [Pg.53]    [Pg.926]    [Pg.935]    [Pg.941]    [Pg.950]    [Pg.950]    [Pg.954]    [Pg.1917]    [Pg.58]    [Pg.60]    [Pg.618]    [Pg.210]    [Pg.575]    [Pg.526]    [Pg.84]    [Pg.128]   
See also in sourсe #XX -- [ Pg.32 ]




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