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Carboalumination internal alkynes

Carboalumination of alkynes is possible in the presence of the zirconium catalyst Cp2ZrCl2. The method is particularly attractive for methylalumination using Me3 A1 and can tolerate a wide variety of functional groups. Terminal alkynes react with very good regioselectivity ( 95 5) and excellent stereoselectivity (>98%) in favour of the alkenyl aluminium species, such as 58 (2.69). Mixtures of regioisomers often result when using internal alkynes with two different substituents. [Pg.132]


See other pages where Carboalumination internal alkynes is mentioned: [Pg.213]    [Pg.394]    [Pg.890]    [Pg.67]    [Pg.16]    [Pg.9]    [Pg.264]    [Pg.151]   
See also in sourсe #XX -- [ Pg.890 ]

See also in sourсe #XX -- [ Pg.4 ]

See also in sourсe #XX -- [ Pg.4 ]




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Carboalumination

Carboalumination alkynes

Internal alkyne

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