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Carbenes generation guest@host

Adamantylidenes, when generated by photolysis of the corresponding diazirines incarcerated within an organic container, were found to behave differently from free carbenes and the chemistry ensuing was determined by the structure of the host-guest complexes. Thus, the substituent pattern on the adamantane skeleton affected the orientation of the carbene within the host cavity. ... [Pg.26]

The reactive behavior of a carbene within a molecular reaction vessel is expected to be very different from that of a carbene in any other reaction medium. Host vessels may have any variety of different channel or cavity sizes that can restrict the mobility of carbene guests and any other reaction partner that might also be included.54 One should even be able to generate, within the host domain, a carbene that has no intramolecular reaction pathways available. Situated like a model ship... [Pg.222]

See other pages where Carbenes generation guest@host is mentioned: [Pg.241]    [Pg.288]    [Pg.303]    [Pg.517]    [Pg.60]   
See also in sourсe #XX -- [ Pg.2 ]

See also in sourсe #XX -- [ Pg.2 ]



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Carbene generation

Host-guest

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