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Carbamates, restricted rotation

There have been a number of recent studies of restricted rotation about C—N bonds. In dialkylthiocarbamyl derivatives of ferrocene, rotation about the C—N carbamate bond was measured by DNMR and barriers were in the range 64.4 to 67.8 kJ mol" for various alkyl derivatives. In the complex (19) dithiocarbamate C—N bond rotation occurs with an energy of 75-84 kJmol . Additionally,... [Pg.350]

See other pages where Carbamates, restricted rotation is mentioned: [Pg.46]    [Pg.89]    [Pg.111]    [Pg.21]    [Pg.1366]    [Pg.989]    [Pg.314]    [Pg.314]    [Pg.527]    [Pg.143]   
See also in sourсe #XX -- [ Pg.21 ]



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Restricted rotation

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