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Capped trigonal prismatic species

We may also mention that there are numerous isocyanide complexes. Isoleptic species are obtained smoothly by the reaction of RNC with Mo2(02CCH3)4 and isolated as [Mo(RNC)7](PF6)2, and in other ways, some of which allow preparation of analogous W" complexes. Substitution of RCN ligands by phosphines, phen, bipy, and so on, lead to many other complexes, particularly the types [M(RCN) L7 ]2+. The [MoX2(CO)4]2 compounds react with RNC to give Mo(RNC)sX2. The [Mo(CNR)6I]+ and [Mo(CNR)7]2+ ions can be made by reaction of Mo(CO)6 with RNC and I2 or by alkylation and reduction of [Mo(CN)8]4. Both types have capped trigonal prismatic geometry. [Pg.953]

See other pages where Capped trigonal prismatic species is mentioned: [Pg.951]    [Pg.1060]    [Pg.343]    [Pg.915]    [Pg.10]    [Pg.43]    [Pg.46]    [Pg.915]    [Pg.293]    [Pg.296]    [Pg.483]    [Pg.486]    [Pg.490]    [Pg.248]    [Pg.1060]    [Pg.665]    [Pg.7060]    [Pg.766]    [Pg.681]    [Pg.3]    [Pg.254]    [Pg.153]    [Pg.1982]    [Pg.537]    [Pg.146]    [Pg.1981]    [Pg.432]    [Pg.122]    [Pg.486]    [Pg.58]    [Pg.60]    [Pg.177]    [Pg.541]    [Pg.185]    [Pg.13]    [Pg.5]   


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Trigonal prismatic species

Trigonal-prismatic

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