Capillary electrochromatography band broadening

Ratnayake, C. K., Oh, C. S., and Henry, M. P. (2000). Characteristics of particle-loaded monolithic sol-gel columns for capillary electrochromatography I. Structural, electrical and band-broadening properties. /. Chromatogr. A 887, 277-285. 

Since a chromatographic mechanism (solute partitioning between two phases moving relative to one another) is involved in micellar capillary electrochromatography, the theory outlined above for band broadening in electrophoresis does not apply. Theoretical aspects of MCE have been developed by Terabe et al. [36] and by Davis [37]. 

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