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Camphor P450 enzymes

Figure 7 12 Conversion of camphor to its 5-exo alcohol counterpart using P450 enzyme. Figure 7 12 Conversion of camphor to its 5-exo alcohol counterpart using P450 enzyme.
The P450 enzyme from Pseudomonas putida (P450cam or C YP101), which hydroxylates camphor to 5-exo-hydroxycamphor has been studied in detail and is regarded as a model protein for other P450s. The electron donor to P450cam is putidaredoxin, which can deliver one electron at a time. In the course of the reaction, an activated oxygen atom from the heme iron is transferred to the unactivated C H bond of the substrate. A Fe(IV)=0 porphyrin-7r-cation radical has been proposed as the key iron-oxo intermediate, compound I (Cpd I), but it has remained elusive so far in studies of the enzyme with substrate ( RH ). [Pg.6569]

See other pages where Camphor P450 enzymes is mentioned: [Pg.340]    [Pg.382]    [Pg.332]    [Pg.519]    [Pg.218]    [Pg.1915]    [Pg.1916]    [Pg.1919]    [Pg.1922]    [Pg.1922]    [Pg.1923]    [Pg.1923]    [Pg.1722]    [Pg.1724]    [Pg.1758]    [Pg.137]    [Pg.78]    [Pg.148]    [Pg.149]    [Pg.593]    [Pg.4]    [Pg.9]    [Pg.63]    [Pg.184]    [Pg.1914]    [Pg.1915]    [Pg.1918]    [Pg.1921]    [Pg.1921]    [Pg.1921]    [Pg.1922]    [Pg.1922]    [Pg.189]    [Pg.113]    [Pg.339]    [Pg.365]    [Pg.873]    [Pg.704]    [Pg.2683]    [Pg.85]    [Pg.94]    [Pg.239]    [Pg.233]    [Pg.172]    [Pg.362]    [Pg.363]   
See also in sourсe #XX -- [ Pg.871 , Pg.873 ]



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Camphorates

Camphore

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