Cadmium sulfoxide complexes

Cadmium nitrate, preparation of, 6 135 Cadmium phthalocyanine electronic absorption spectra of, 7 68 preparation of, 7 41 Cadmium selenocyanates, 17 337 Cadmium sulfoxide complexes, 24 167-168... [Pg.35]

Much work has been devoted to the halide complexation of these elements in non-aqueous media. Equilibrium and calorimetric measurements for the formation of the [MX ](n-2) (M = Zn or Cd X = Cl, Br, I or SCN n = 1-4) anions in dimethyl sulfoxide (DMSO) have shown that stability constants follow the same order, but are much larger than those found for aqueous solution zinc exhibits an enhanced hardness as an acceptor in DMSO as compared to cadmium. Calorimetric measurements indicate a change from octahedral to tetrahedral coordination with increasing halide concentrations.1002-1006... [Pg.985]

Sandstrom M (1977) An X-ray diffraction and Raman study of mercury(II) chloride complexes in aqueous solution. Evidence for the formation of polynuclear complexes. Acta Chem Scand Ser A 31 141-150 Sandstrom M, Persson I, Ahrland S (1978) On the coordination around mercuiy(II), cadmium(II) and zinc(II) in dimethyl sulfoxide and aqueous solutions. An X-ray diffraction, Raman and infrared investigation. Acta Chem Scand Ser A 32 607-625... [Pg.98]

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