C1NO Nitrosyl chloride

The same workers also prepd trifluoronitrosomethane by the reaction of Ag trifluoroacetate with nitrosyl chloride (C1NO), yield 13% (Ref... 

U. NITROSYL CHLORIDE (C1NO) AND NITRYL CHLORIDE (C1NQ )... 

Figures 4.42 and 4.43 show the absorption spectra of nitrosyl chloride (C1NO) and nitryl chloride (C1N02), respectively (Roehl et al., 1992 Ganske et al., 1992), and Tables 4.35 and 4.36 list the recommended room temperature absorption cross sections (DeMore et al., 1997). In both cases, chlorine atoms are produced with unit quantum yield ...

The conditions under which HC1 formed in acidified sodium chloride droplets would be expected to enter the gas phase have been treated by Clegg and Brimble-combe (1990). Cadle and co-workers (Robbins et al., 1959 Cadle and Robbins, 1960) observed that NaCl aerosols in the presence of 0.1-100 ppm NOz at relative humidities of 50-100% lost chloride ion from the particles. They ascribed this to the formation of nitric acid from NOz, followed by reaction (1). Schroeder and Urone (1974) subsequently suggested that NOz could react directly with NaCl to produce gaseous nitrosyl chloride, C1NO, which they observed using infrared spectroscopy stoichiometrically, this is represented as... 

The picture is somewhat further complicated by more recent shock-tube results, obtained by Deklau and Palmer,115 on the decomposition of nitrosyl chloride over the temperature range 880-1350°K. Deklau and Palmer made the untenable assumption that in the presence of C1NO and argon, the rate law could be written as... 

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