Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

2- Butene carbene insertion into

Difluorocarbene generated by the thermolysis of trimethyltnfluoromethylsilane reacts with disilanes by insertion into the silicon-silicon bond [S] (equation 9) Thermolysis of pentafluoroethyltnfluorosilane at 200 °C gives tetrafluoro ethylidene carbene, which reacts with phosphorus trifluonde to give trifluoro vinyltetrafluorophosphorane [9] (equation 10) and with perfluorotnmethylphos-phine to give perfluorodimethyhsopropylphosphine and perfluoro-2-butene [9] (equation 10)... [Pg.499]

Acetylenes also react with alkylidene complexes to afford a new carbene derivative formed by inserting the triple bond into the alkylidene-metal bond . A metallacyclo-butene is the intermediate species ... [Pg.94]

See other pages where 2- Butene carbene insertion into is mentioned: [Pg.25]    [Pg.18]    [Pg.227]    [Pg.414]    [Pg.227]    [Pg.654]    [Pg.227]    [Pg.654]    [Pg.227]    [Pg.1204]   
See also in sourсe #XX -- [ Pg.200 ]



SEARCH



Carbene insertion

Carbenes insertion

Carbenes insertion into

Insertion into

© 2024 chempedia.info