Buckingham effect

Rizzo reviews in a unitary framework computational methods for the study of linear birefringence in condensed phase. In particular, he focuses on the PCM formulation of the Kerr birefringence, due to an external electric field yields, on the Cotton-Mouton effect, due to a magnetic field, and on the Buckingham effect due to an electric-field-gradient. A parallel analysis is presented for natural optical activity by Pecul Ruud. They present a brief summary of the theory of optical activity and a review of theoretical studies of solvent effects on these properties, which to a large extent has been done using various polarizable dielectric continuum models. 

In the next section we summarize the theoretical background for coupled cluster response theory and discuss certain issues related to their actual implementation. In Sections 3 and 4 we describe the application of quadratic and cubic response in calculations of first and second hyperpolarizabilities. The use of response theory to calculate magneto-optical properties as e.g. the Faraday effect, magnetic circular dichroism, Buckingham effect, Cotton-Mouton effect or Jones birefringence is discussed in Section 5. Finally we give some conclusions and an outlook in Section 6. 

This result was first discussed by Buckingham (8) and stated in its present form by Langhaar (23). It states in effect that an equation is dimensionally homogeneous if and only if it can be reduced to a relationship among a complete set of B-numbers. Buckingham s result (8) was originally stated as Theorem 2. 

Brunsveld, L., Chiral Discotic Molecules Expression and Amplification of Chirality, 24, 373. Buckingham, D. A., Conformational Analysis and Configurational Effects for Chelate Complexes, 6, 219. 

Bubbly liquid, structure of, 12 7 Buccal drug dehvery, 9 48 Bucherer reaction, 9 279 Bucherer synthesis, 2 571 Buchner, Edward, 11 8 Buckingham s theorem, 3 589 Buckingham Pi theorem, 11 744 Buckminsterfullerene (Ceo), 22 719 photovoltaic effects in, 22 220 Buckminsterfullerenes, 4 735 12 228. 

Buckingham, A. D., Schaefer, T., Schneider, W. G. Solvent Effects in Nuclear Magnetic Resonance Spectra. J. Chem. Phys. 32, 1227 (1960). 

Metal Chelates, Conformational Analysis and Steric Effects in (Buckingham and Sargeson) 6 219... 

Rawjee, YY, Williams, R.L., Buckingham, L.A., Vigh, G Effects of pH and hydroxypropyl fS-cyclodextrin concentration on peak resolution in the capillary electrophoretic separation of the enantiomers of weak bases. J. Chromatogr. 1994, 688, 273-282. 

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