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Brutto-reaction, detailed mechanism and the number of parameters under determination

5 BRUTTO-REACTION, DETAILED MECHANISM AND THE NUMBER OF PARAMETERS UNDER DETERMINATION [Pg.241]

This section is devoted to the relation between the brutto (stoichiometric) equation corresponding to the detailed mechanism and the structure of a kinetic equation. Note that all the detailed mechanisms above can conventionally be divided into two classes. (This division will be applied in what follows.) [Pg.241]

Mechanisms of class 1. This is a well-known Michaelis-Menten scheme [Pg.241]

It is the one-route mechanism for hydrogen oxidation on the oxides of Group IV transition metals [38] [Pg.242]

A mechanism of this class is also a one-route scheme for S02 oxidation over vanadium catalysts having a buffer step [61] [Pg.242]



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And mechanism of reaction

BRUTTO

Detailed mechanism

Detailed reaction mechanisms

Determination of mechanical

Determination of mechanisms

Determination of reaction mechanisms and

Determinations, number

Determining reaction mechanisms

Mechanical details

Mechanical parameters

Mechanically determined

Mechanism determination

Mechanisms of the Reaction

Number of parameters

Parameter determination

Reaction determination

Reaction mechanisms determination

Reaction number

Reaction parameter

Reactions numbering

The Reaction Mechanism

The parameters

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