Brownian motion stochastic coupling

In general, fluctuations in any electron Hamiltonian terms, due to Brownian motions, can induce relaxation. Fluctuations of anisotropic g, ZFS, or anisotropic A tensors may provide relaxation mechanisms. The g tensor is in fact introduced to describe the interaction energy between the magnetic field and the electron spin, in the presence of spin orbit coupling, which also causes static ZFS in S > 1/2 systems. The A tensor describes the hyperfine coupling of the unpaired electron(s) with the metal nuclear-spin. Stochastic fluctuations can arise from molecular reorientation (with correlation time Tji) and/or from molecular distortions, e.g., due to collisions (with correlation time t ) (18), the latter mechanism being usually dominant. The electron relaxation time is obtained (15) as a function of the squared anisotropies of the tensors and of the correlation time, with a field dependence due to the term x /(l + x ). 

The theory of relaxation processes for a macromolecular coil is based, mainly, on the phenomenological approach to the Brownian motion of particles. Each bead of the chain is likened to a spherical Brownian particle, so that a set of the equation for motion of the macromolecule can be written as a set of coupled stochastic equations for coupled Brownian particles... 

When one is interested in slow modes of motion of the system, each macromolecule of the system can be schematically described in a coarse-grained way as consisting of N + 1 linearly-coupled Brownian particles, and we shall be able to look at the system as a suspension of n(N + 1) interacting Brownian particles. An anticipated result for dynamic equation of the chains in equilibrium situation can be presented as a system of stochastic non-Markovian equations... 

To recover the ideal case of Eq. (1.1) we would have to assume that (u ), vanishes. The analog simulation of Section III, however, will involve additive stochastic forces, which are an unavoidable characteristic of any electric circuit. It is therefore convenient to regard as a parameter the value of which will be determined so as to fit the experimental results. In the absence of the coupling with the variable Eq. (1.7) would describe the standard motion of a Brownian particle in an external potential field G(x). This potential is modulated by a fluctuating field The stochastic motion of in turn, is driven by the last equation of the set of Eq. (1.7), which is a standard Langevin equation with a white Gaussian noise defined by... 

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