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2-Bromocyclohexyl brosylate

A preliminary indication that bromonium ions could be formed reversibly was provided by the reaction of adamantylideneadamantane (p. 249) leading to a highly stable bromonium-tribromide ion pair that readily releases bromine and the initial alkene (Strating et al, 1969). However, the first evidence for possible return came from the acetolysis of 2-bromocyclohexyl-brosylate in the presence of bromide ions. It was shown (Brown et al, 1984) that the cyclohexylbromonium ion intermediate is able to release bromine. The drastic reaction conditions (high temperature, long duration and high bromide concentrations) cast some doubt on the generality of this observation. [Pg.280]


See other pages where 2-Bromocyclohexyl brosylate is mentioned: [Pg.33]    [Pg.33]   
See also in sourсe #XX -- [ Pg.911 ]

See also in sourсe #XX -- [ Pg.911 ]




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2-bromocyclohexyl

Brosylate

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