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Bromo-methane temperature

Xenon difluoride reacts also with some halosubstituted alkanes18,19 at room temperature in chloroform, carbon tetrachloride, dichloromethane or bromoform, and depending on the nature of the solvent used chloro or bromo derivatives are isolated with imidazo-(l,2-fr)-pyridazine18. Carbon tetrachloride reacts with xenon difluoride at 180°C, while room-temperature transformations are achieved when various catalysts [antimony trifluoride, tantalum(V) fluoride or silica dioxide] are used, whose structure also influences the product distribution20. Tris(fluorosulfonyl)methane gives a fluoro-substi-tuted product in its reaction with xenon difluoride in difluorodichloromethane21. [Pg.825]


See other pages where Bromo-methane temperature is mentioned: [Pg.460]    [Pg.453]    [Pg.27]    [Pg.141]    [Pg.83]    [Pg.102]    [Pg.75]    [Pg.75]    [Pg.179]   


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