Bromley multicomponent solution

A common failing of earlier work on multicomponent solutions was to consider the 3R,x to be a constant for each salt. As Bromley (5) pointed out, the equations developed from the... [Pg.231]

Bromley felt that treating a multicomponent solution as a single complex salt solution would be the simplest approach towards calculating the activity coefficients of electrolytes in solution. The Fj terms would then be based on the ionic interactions of this "complex salt". Using the convention that odd number subscripts denote cations and even number subscripts indicate anions, he proposed for a cation ... [Pg.211]

In 1973, Bromley (B3) disputed Meissner and Kusik s method for multicomponent solutions as follows ... [Pg.215]

Meissner and Kusik (M7) revised their method for calculating the activity coefficients of electrolytes in multicomponent solutions in 1978. They extended equation (5.16) in order to avert the problem pointed out by Bromley. For an electrolyte of cation i and anion j, the reduced activity coefficient is ... [Pg.217]

Bromley s (S) method of calculating the activity coefficients of ionic species in multicomponent solutions, detailed in Chapter V. leads to the following equations ... [Pg.598]

The second assumption was also made by relying on the low solubility. Recalling from Chapter V Bromley s <5) equations for the activity coefficient of a single ion in a multicomponent solution ... [Pg.655]

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