Bromine covalent radius

Just as the size of an orbital cannot be specified exactly, neither can the size of an atom. We must make some arbitrary choices to obtain values for atomic radii. These values can be obtained by measuring the distances between atoms in chemical compounds. For example, in the bromine molecule, the distance between the two nuclei is known to be 228 pm. The bromine atomic radius is assumed to be half this distance, or 114 pm, as shown in Fig. 7.34. These radii are often called covalent atomic radii because of the way they are determined (from the distances between atoms in covalent bonds). 

A The covalent radius of bromine is one-half the distance between two bonded bromine atoms. 

After rising at copper and zinc, the curve of metallic radii approaches those of the normal covalent radii and tetrahedral covalent radii (which themselves differ for arsenic, selenium, and bromine because of the difference in character of the bond orbitals, which approximate p orbitals for normal covalent bonds and sp3 orbitals for tetrahedral bonds). The bond orbitals for gallium are expected to be composed of 0.22 d orbital, one s orbital, and 2.22 p orbitals, and hence to be only slightly stronger than tetrahedral bonds, as is indicated by the fact that R(l) is smaller than the tetrahedral radius. 

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