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Brillouin-Wigner perturbation

In the Brillouin-Wigner perturbation formalism, the following identity is used... [Pg.242]

Here we ignore any possible perturbation to the site energies at the ends of the chain, n = 1 and n = m.) We apply Brillouin-Wigner perturbation theory (Ohanian 1990), whereby the eigenvalue of a non-degenerate state can be expressed as... [Pg.120]

Lennard-Jones Brillouin Wigner Perturbation Theory.—Let us write the total hamiltonian operator as a sum of a zero-order operator and a perturbation... [Pg.5]

In Lennard-Jones Brillouin Wigner perturbation theory the wave operator is written as... [Pg.6]

Explicitly, the first few terms in the Lennard-Jones Brillouin Wigner perturbation series take the form... [Pg.6]

The Lennard-Jones Brillouin Wigner perturbation expansion is a simple geometric series. However, it contains the unknown exact energy within the denominators. This expansion is, therefore, not a simple power series in the perturbation. [Pg.6]

Appendix 6. Brillouin-Wigner Perturbation Theory of the Quasi-species. Appendix 7. Renormalization of the Perturbation Theory Appendix 8. Statistical Convergence of Perturbation Theory Appendix 9. Variables, Mean Rate Constants, and Mean Selective Values for the Relaxed Error Threshold... [Pg.150]

APPENDIX 6. BRILLOUIN-WIGNER PERTURBATION THEORY OF THE QUASI-SPECIES... [Pg.255]

C. Huber, and R. J. Bartlett. Integral packages included are VMOL (J. Almlof and P. R. Taylor) VPROPS (P. R. Taylor) ABACUS (T. Helgaker, H. J. Aa Jensen, P. Jprgensen, J. Olsen, and P. R. Taylor). Brillouin-Wigner perturbation theory was implemented by J. Pittner. [Pg.262]

Multireference coupled cluster method based on the Brillouin-Wigner perturbation theory... [Pg.465]

Our interest in Brillouin-Wigner perturbation theory was stimulated by our finding [44] that this theoretical tool proved very useful in the scattering theory. The fundamental equation, known in the scattering theory as Lippmann-Schwinger equation, expresses the scattering operator as... [Pg.470]

Elimination of the size-extensivity error in the MRBWCC theory was suggested by Hubac and Wilson [68]. The Brillouin-Wigner perturbation theory has been known notoriously as a method not furnishing size extensivity. There was therefore every reason to believe that the size-extensivity error in MR BWCCSD originated from the use of the Brillouin-Wigner type resolvent (15) instead of the Rayleigh-Schrodinger... [Pg.474]


See other pages where Brillouin-Wigner perturbation is mentioned: [Pg.77]    [Pg.93]    [Pg.149]    [Pg.155]    [Pg.77]    [Pg.8]    [Pg.20]    [Pg.209]    [Pg.256]    [Pg.308]    [Pg.211]    [Pg.259]    [Pg.466]    [Pg.470]    [Pg.470]    [Pg.471]    [Pg.471]   
See also in sourсe #XX -- [ Pg.120 ]




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