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Bridging metal-hydrogen bonds

Scheme 1 Co-ordinative (a pendant d-f bridging) and hydrogen-bonded (b, c, e, g-i) contacts observed in complexes containing both 4,4 -bipyridine-)V,lV -dioxide and a Scheme 1 Co-ordinative (a pendant d-f bridging) and hydrogen-bonded (b, c, e, g-i) contacts observed in complexes containing both 4,4 -bipyridine-)V,lV -dioxide and a </-block transition metal, M. The number quoted is the frequency of observation in a total of 98 examples. For those systems with a single hydrogen-bonded contact at each end of the 4,4 -bipyridine-lV,Af -dioxide (g), the majority (7) lie across an inversion centre giving a pseudo anri-conformation arrangement as shown above...
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See also in sourсe #XX -- [ Pg.89 ]



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Bridge bond

Bridge-bonding

Hydrogen bridge bonds

Hydrogen bridged bond

Hydrogen bridges

Hydrogen metal bonding

Metal bridged

Metal-hydrogen bond

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