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Bridgehead Carbon Free Radicals

Many free-radical reactions have been observed at bridgehead carbons (e.g., see 14-37), ... [Pg.904]

Many free-radical reactions have been observed at bridgehead carbons, as in formation of bromide 18 (see 14-30), ° demonstrating that the free radical need not be planar. However, treatment of norbomane with sulfuryl chloride and benzoyl... [Pg.949]

Another approach to obtaining information about the geometric requirements of free radicals has been to examine bridgehead systems. It will be recalled that the small bicyclic rings strongly resist formation of carbonium ions at bridgehead carbon atoms because the skeletal geometry prevents attainment of the preferred planar... [Pg.514]

See other pages where Bridgehead Carbon Free Radicals is mentioned: [Pg.42]    [Pg.42]    [Pg.244]    [Pg.77]    [Pg.733]    [Pg.568]    [Pg.592]    [Pg.192]    [Pg.46]    [Pg.786]    [Pg.277]    [Pg.152]    [Pg.685]    [Pg.951]    [Pg.640]   


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Bridgehead

Bridgehead carbons

Bridgehead radicals

Carbon free

Carbon radicals

Carbonate radical

Free Radicals, carbon

Free radicals bridgehead

Free radicals carbonate

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