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Bridged macrocyclic transition metal

Table 15.6 Room Temperature Powder Conductivities of Monomeric and Bridged Macrocyclic Transition Metal Complexes ... Table 15.6 Room Temperature Powder Conductivities of Monomeric and Bridged Macrocyclic Transition Metal Complexes ...
ABSTRACT. Bridged macrocyclic transition metal complexes using phthalo-cyanine and naphthalocyanine as macrocycles e.g. [PcML] with M = Fe, Ru Co and L = dib, tz, CN show good semi-conducting properties without external doping. The mechanism of the formation of the bridged macro-cyclic metal complexes is studied by H-NMR spectroscopy using the monomer PcFe(Me dib) . [Pg.173]

BRIDGED MACROCYCLIC TRANSITION METAL COMPLEXES WITH MACROCYCLIC LIGANDS... [Pg.705]

Table 13.7 Room temperature powder conductivities of monomeric and bridged macrocyclic transition metal complexes (pressed pellets, 10 Pa) [14]... Table 13.7 Room temperature powder conductivities of monomeric and bridged macrocyclic transition metal complexes (pressed pellets, 10 Pa) [14]...
Figure 1. Schematic structure of bridged macrocyclic transition metal complexes... Figure 1. Schematic structure of bridged macrocyclic transition metal complexes...
A review13 with 53 references of the transition-metal mediated supramolecular self-assembly is presented. Focus is on the self-assembly of macrocycles, catenanes, and cages from (en)Pd(N03)2 and pyridine-based bridging ligands. [Pg.557]

An 18-membered N3O3 macrocycle could not be synthesized with transition metal templates but the N402 analog (85) was successfully synthesized with a zinc template. This gave dinuclear /r-hydroxy bridged zinc complexes including a rare example of a single unsupported... [Pg.1210]

Transition metal complexes of the larger polyaza macrocyclic ligands have been less extensively studied than for the smaller ring systems. For the pentaaza macrocycles, [ISJaneNs with ethylene bridges appears to form the most stable complexes with most metal ions. Structural data for a variety of pentaaza macrocyclic complexes have been reviewed. The N-H bonds as well as the different sized chelate rings must be considered in calculating the... [Pg.2428]

Dinucleating macrocycles such as L23 and L24 (Fig. 26) provide two transition metal coordination sites and impose di-/[i-phenoxo bridging. Nickel(II) ions are coordinated by two imine nitrogen donors and the two bridging phenoxides in an essentially planar array and pseudo-... [Pg.355]

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Bridged macrocyclic complexes with trivalent transition metal ions

Bridged macrocyclic transition metal complexes

Macrocycle, metalation

Macrocycles metals

Metal bridged

Metal macrocyclics

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