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Bridge-terminal CO exchange

The phenomenon of bridge-terminal carbonyl exchange can occur in any dimetal system that can exist in CO-bridged and metal-metal bonded forms, such as COjfCO), ... [Pg.141]

From the values of T,M and B calculated in this way we may note that for both iron and cobalt M 0.68 T and that B 0.5 T. The latter approximation is intuitively consistent with the observations22 of bridge-terminal exchange of coordinated CO. If we now assume that these empirical approximations apply to other polynuclear carbonyls, it is possible to extract the T and M- values for metals other than iron and cobalt, despite the limited AHo data which are available. [Pg.80]

See other pages where Bridge-terminal CO exchange is mentioned: [Pg.239]    [Pg.323]    [Pg.361]    [Pg.335]    [Pg.408]    [Pg.141]    [Pg.228]    [Pg.150]    [Pg.160]    [Pg.422]    [Pg.422]    [Pg.265]    [Pg.622]    [Pg.239]    [Pg.323]    [Pg.361]    [Pg.335]    [Pg.408]    [Pg.141]    [Pg.228]    [Pg.150]    [Pg.160]    [Pg.422]    [Pg.422]    [Pg.265]    [Pg.622]    [Pg.136]    [Pg.217]    [Pg.314]    [Pg.172]    [Pg.938]    [Pg.324]    [Pg.330]    [Pg.361]    [Pg.384]    [Pg.367]    [Pg.33]    [Pg.428]    [Pg.450]    [Pg.353]    [Pg.139]    [Pg.269]    [Pg.358]    [Pg.236]    [Pg.323]    [Pg.90]    [Pg.261]    [Pg.379]    [Pg.123]    [Pg.314]    [Pg.212]   
See also in sourсe #XX -- [ Pg.141 ]



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Bridging-terminal CO exchange

Bridging-terminal CO exchange

Co , bridged

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