Bridge potential

Table IV lists the redox potentials of conjugated ferrocene oligomers (mainly dimers with a single bridge). Potential values are denoted against different reference electrodes as given in the references. The values can be primarily compared using the relationship mentioned in the footnote of the table, although care should be taken with some errors derived from junction potentials which depend on experimental conditions. There have been several reports on the quantitative estimation of structural factors affecting internuclear electron delocalization.

Fulcrand, H. et al., An oxidized tartaric acid residue as a new bridge potentially competing with acetaldehyde in flavan-3-ol condensation. Phytochemistry 46, 223, 1997. 

The examination of Eq. (C.12) shows that when k = 1, the operator given by Eq. (C.2) displaces the origin used for the kets, thus the name translation operator . In order to visualize this displacement of the position of the H-bond bridge potential in representation III when the fast mode has jumped from its ground state 0 ) to its first excited state 1 ), it is more suitable to represent it by a Morse-like one. This is performed in Fig. 2. 

Figure 7.88 (a) Area B of Figure 7.87a, showing that the gap-bridging potential of the newly formed bone is reduced when the distance between the coated implant and surrounding cortical bone is increased, (b)... 

---