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Braverman

J. Robbins and L. E. Braverman, eds.. Thyroid Kesearch 7th International Thyroid Conference, Excerpta Medica, Amsterdam, the Netherlands, 1976. [Pg.54]

MISLOW BRAVERMAN EVANS Rearrangemenl Reversible 2.3- sigmatiopic rearrangement o( aHyUc sulloxides to ailyl suVenates which are cleaved by phosphites to allyUc alcohols. [Pg.266]

Taurog A (2000) Thyroid hormone synthesis Thyroid iodine metabolism. In Braverman LE, Utiger RD (eds) Werner and Ingbar The thyroid. Lippincott Williams Wilkins, Philadelphia, PA, pp 61-85... [Pg.192]

Fuhrer D, Krohn K, Paschke R (2005) Toxic Adenoma and toxic Multinodular Goiter. In Braverman, LE Utiger (Hrsg.) RD (eds) Lippincott Williams Wilkins, ISBN 0-7817-5047-4, The Thyroid, 508-518... [Pg.192]

The spontaneous rearrangement of allyl p-toluenesulphenates to allyl sulphoxides was independently recorded by Mislow and coworkers and Braverman and Stabinsky. Mislow and colleagues201 have demonstrated that simple allyl alcohols such as 149, on conversion to the corresponding lithium alkoxides followed by treatment with arenesulphenyl chlorides, may be smoothly transformed at room temperature via the sulphenate esters into allylic sulphoxides 150 (equation 83). Braverman and Stabinsky202 have found that when the more reactive trichloromethanesulphenyl chloride is treated with allyl alcohol and pyridine in ether at — 70°, it affords trichloromethyl allyl sulphoxide and not allyl trichloromethanesulphenate as reported by Sosnovski203 (equation 84). [Pg.270]

The allyl sulphenate-allyl sulphoxide rearrangement is a general reaction and is applicable to structurally diverse allyl alcohols204,205 (Table 13). Mechanistically, it represents a typical example of a [2,3]-sigmatropic rearrangement as shown by the detailed investigations of Mislow and Braverman and their coworkers. [Pg.270]

Braverman and Grendi206 have shown that, depending on the type of substitution, allylic trichloromethanesulphenates undergo rearrangement to allylic trichloromethyl sulphoxides by one of two different pathways (equation 85). Rearrangement according to route a has been observed with allyl, crotyl and a, a-dimethylallyl sulphenates. It occurs... [Pg.271]

On the basis of the evidence presented above as well as some other pertinent data (e.g. negative entropies of activation), Darwish and Braverman have suggested that the rearrangement of allylic 2,6-dimethylbenzenesulfinates (6a-f) to corresponding sulfones (7a-f) proceeds by a cyclic intramolecular mechanism involving a five-membered transition state which may be represented by a resonance hybrid (8) of the following resonance structures. [Pg.673]

Following studies on the rearrangement of allylic arenesulfinates, Braverman and coworkers have investigated a number of natural extensions of this unique transformation, including the predictable [2,3] sigma tropic rearrangements of allylic sulfenates to sulfoxides and of propargylic sulfenates and sulfinates to allenic sulfoxides and sulfones respectively. The last reaction is described below, while the other two are described in Chapter 14. [Pg.676]

Braverman and Reisman111 have found that addition of a carbon tetrachloride solution of bromine to bis-y,y-dimethylallenyl sulfone 20 at room temperature unexpectedly resulted in spontaneous and quantitative fragmentation of the sulfone, with formation of the cyclic a, /3-unsaturated sulfmate (y-sultine) 43a and the tribromo products 44 and 45 (equation 38). Analogously, treatment of the same sulfone with trifluoroacetic acid gives rise to y-sultine 43b. It is interesting to note that from a synthetic point of view it is not even necessary to prepare the diallenyl sulfone 20, since one can use its sulfinate precursor (equation 24) to obtain exactly the same results, under the same conditions. The authors suggested that the fragmentation-cyclization of sulfone 20 may take place by the mechanism depicted in equation 39. [Pg.683]


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See also in sourсe #XX -- [ Pg.266 ]

See also in sourсe #XX -- [ Pg.147 ]

See also in sourсe #XX -- [ Pg.244 ]

See also in sourсe #XX -- [ Pg.248 ]

See also in sourсe #XX -- [ Pg.248 ]




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Braverman, Harry

MISLOW BRAVERMAN - EVANS

MISLOW BRAVERMAN - EVANS Rearrangement

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