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Borohydride complexes, osmium

The synthesis and chemistry of an 7] -selenophene osmium complex 50 has been studied <19990M1559>. Protonation and electrophilic substitution with acetaldehyde diethyl acetal occurred at C-2. Methylation of complex 50 with methyl triflate gave 51 which upon treatment with tetrabutylammonium borohydride (TBAB) led to the selenophene ring-opened complex 52 (Scheme 5). [Pg.984]


See other pages where Borohydride complexes, osmium is mentioned: [Pg.177]    [Pg.400]    [Pg.222]    [Pg.400]    [Pg.555]    [Pg.3363]    [Pg.3362]    [Pg.555]    [Pg.4009]    [Pg.236]    [Pg.422]    [Pg.326]    [Pg.452]   
See also in sourсe #XX -- [ Pg.299 ]




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Borohydride complexes

Osmium complexes

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