Borato complexes iron

Synthesis, crystal structure, and reactivity of a four-coordinate iron(II) chloride complex bearing the sterically demanding tert-butyl-tris (3 -isopropylpyrazolyl) borato ligand... [Pg.507]

Recently, iron(V) nitride complex [PhB( Bulm)3Fe =N]BArF24 (PhB( Bulm)3 = phenyltris(3-tert-butylimidazol-2-ylidene)borato BArp24 = B(3,5-(CF3)2QH3)4 ) has been prepared [100]. This complex has a four-coordinate iron ion with a terminal nitride ligand. The characterization of the complex by Mossbauer and electron paramagnetic resonance spectroscopy demonstrated d iron(V) metal center in a low-spin (S= 1/2) electron configuration. The decomposition of the complex by water at low temperature formed ammonia and iron(ll) species. [Pg.511]

Jove FA, Pariya C, Scoblete M, Yap GPA, Theopold KH. A family of four-coordinate iron(II) complexes bearing the stericaUy hindered tris(pyrazolyl)borato ligand Tp . Chem EmJ. 2011 17 1310-1318. [Pg.250]

See also in sourсe #XX -- [ Pg.17 , Pg.139 , Pg.140 , Pg.141 , Pg.142 , Pg.143 , Pg.144 , Pg.145 , Pg.146 ]

See also in sourсe #XX -- [ Pg.17 , Pg.139 , Pg.140 , Pg.141 , Pg.142 , Pg.143 , Pg.144 , Pg.145 , Pg.146 ]

See also in sourсe #XX -- [ Pg.17 , Pg.139 , Pg.140 , Pg.141 , Pg.142 , Pg.143 , Pg.144 , Pg.145 , Pg.146 ]

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