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Bonds 7t-type

The NF3 molecule has two extra electrons, compared to BF3, which would occupy an anti-bonding 7t-type 2a/ orbital if it had a trigonally planar shape. The C1F3 molecule with another two electrons would make use of the anti-bonding or-type 4a,7 orbital if the molecule were to be trigonally planar. It is to avoid use of anti-bonding orbitals that they adopt different symmetries. [Pg.130]

Fig. 1. Pyramidalization of Esterenolate 107 (View along the cyclopropane C-l/C-2 bond, 7t-type orbital in front, a -orbital of the C-2/OR-bond behind)... Fig. 1. Pyramidalization of Esterenolate 107 (View along the cyclopropane C-l/C-2 bond, 7t-type orbital in front, a -orbital of the C-2/OR-bond behind)...

See other pages where Bonds 7t-type is mentioned: [Pg.83]    [Pg.704]    [Pg.3]   
See also in sourсe #XX -- [ Pg.91 , Pg.104 ]




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