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Bond lengths thiocyanate complexes

Figure 3 Bond lengths and bond angles are indicated in the right part of the figure, torsion angles in the left part for the complex of nonactin with sodium thiocyanate. Figure 3 Bond lengths and bond angles are indicated in the right part of the figure, torsion angles in the left part for the complex of nonactin with sodium thiocyanate.
Subsequently it was shown that the P-Pd-P angles were essentially the same as in the corresponding chloride complexes (section 3.8.3) as a result, as the P—Pd—P angle increases, concomitant upon the increase in the length of the methylene chain, steric effects enforce N-bonded thiocyanate, which is less sterically demanding that the non-linear Pd-SCN linkage (favoured on HSAB considerations since Pd2+ is a soft acid and sulphur is a soft base). [Pg.232]


See other pages where Bond lengths thiocyanate complexes is mentioned: [Pg.725]    [Pg.105]    [Pg.111]    [Pg.1362]    [Pg.1138]    [Pg.36]    [Pg.87]    [Pg.639]    [Pg.579]    [Pg.4222]    [Pg.135]    [Pg.747]    [Pg.205]    [Pg.13]    [Pg.250]    [Pg.41]    [Pg.4221]    [Pg.579]    [Pg.681]    [Pg.51]    [Pg.102]    [Pg.1285]    [Pg.1950]    [Pg.3201]    [Pg.4033]    [Pg.6011]    [Pg.901]    [Pg.429]    [Pg.648]    [Pg.649]    [Pg.212]    [Pg.1138]    [Pg.185]    [Pg.277]    [Pg.6011]    [Pg.519]    [Pg.145]   
See also in sourсe #XX -- [ Pg.123 , Pg.231 , Pg.293 , Pg.295 ]

See also in sourсe #XX -- [ Pg.123 , Pg.231 , Pg.293 , Pg.295 ]

See also in sourсe #XX -- [ Pg.123 , Pg.231 , Pg.293 , Pg.295 ]

See also in sourсe #XX -- [ Pg.123 , Pg.231 , Pg.293 , Pg.295 ]




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Bond lengths complexes

Thiocyanate complexes

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