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Bond lengths nitrosyl complexes

Table 5.25. Comparative binding energies AE, intermodular charge transfer Qcv, bond lengths, and 0c-.no angle of nitrosyl n-it CT complexes... Table 5.25. Comparative binding energies AE, intermodular charge transfer Qcv, bond lengths, and 0c-.no angle of nitrosyl n-it CT complexes...
Fig. 7 also shows that base binding in the trans position weakens the metal to nitrosyl backbonding in that the Fe-NO bond length increases by 0.3 A and the Fe-N-O bond angle decreases 9°. In concert with this, the displacement of the Fe from the porphyrin plane decreases from 0.21 A in the square pyramidal structure to 0.07 A in the octahedral complex. The equilibria of NO binding to hemes is summarized in Fig. 8 [64], which indicates that NO binds to Fe" better... [Pg.172]

See other pages where Bond lengths nitrosyl complexes is mentioned: [Pg.77]    [Pg.133]    [Pg.363]    [Pg.57]    [Pg.163]    [Pg.78]    [Pg.160]    [Pg.459]    [Pg.338]    [Pg.235]    [Pg.202]    [Pg.203]    [Pg.162]    [Pg.290]    [Pg.215]    [Pg.549]    [Pg.1104]    [Pg.1116]    [Pg.1192]    [Pg.1974]    [Pg.2133]    [Pg.107]    [Pg.338]    [Pg.1299]    [Pg.107]    [Pg.305]    [Pg.306]    [Pg.329]    [Pg.610]    [Pg.315]    [Pg.652]    [Pg.279]    [Pg.323]    [Pg.324]    [Pg.1973]    [Pg.2132]    [Pg.549]    [Pg.1104]    [Pg.2298]    [Pg.4003]    [Pg.4558]    [Pg.4570]    [Pg.4646]    [Pg.78]    [Pg.11]    [Pg.12]   
See also in sourсe #XX -- [ Pg.46 , Pg.136 , Pg.165 ]

See also in sourсe #XX -- [ Pg.46 , Pg.136 , Pg.165 ]

See also in sourсe #XX -- [ Pg.46 , Pg.136 , Pg.165 ]

See also in sourсe #XX -- [ Pg.46 , Pg.136 , Pg.165 ]



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