Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Bond distances metal-nitrogen

The nitrogen atom in the (almost) linear metal-thionitrosyl complexes is 5p-hybridized and the NS ligand behaves as a three-electron donor. The N-S bond distances in metal complexes vary between 1.45... [Pg.124]

At the same time the bond angles (C—N—C) at the N7 position vary from 112 (-fp3 as expected for an amine ligand) in the manganese complex (where repulsion is least) up to a maximum value of 120 in the iron complex with maximum repulsions. The tertiary amine nitrogen atom (N7) corresponds to a three-ribbed umbrella that has been inverted by the wind (the handle is the lone pair directed at the metal). As the a, and If levels fill, the repulsions increase, the metal-nitrogen distance increases, and the umbrella begins to flatten ... [Pg.795]

See other pages where Bond distances metal-nitrogen is mentioned: [Pg.122]    [Pg.83]    [Pg.136]    [Pg.3]    [Pg.31]    [Pg.22]    [Pg.24]    [Pg.415]    [Pg.1172]    [Pg.78]    [Pg.213]    [Pg.6]    [Pg.327]    [Pg.329]    [Pg.234]    [Pg.11]    [Pg.269]    [Pg.463]    [Pg.2]    [Pg.251]    [Pg.38]    [Pg.275]    [Pg.517]    [Pg.518]    [Pg.162]    [Pg.235]    [Pg.322]    [Pg.68]    [Pg.681]    [Pg.17]    [Pg.132]    [Pg.148]    [Pg.221]    [Pg.243]    [Pg.284]    [Pg.284]    [Pg.1341]    [Pg.265]    [Pg.265]    [Pg.297]    [Pg.458]    [Pg.1075]    [Pg.210]    [Pg.104]    [Pg.120]    [Pg.124]    [Pg.127]    [Pg.135]   
See also in sourсe #XX -- [ Pg.60 ]



SEARCH



Bond distances

Bonding bond distance

Bonding metal-nitrogen

Metal distance

Metal nitrogen

Metal-nitrogen distances

Metals metal-nitrogen bond

© 2024 chempedia.info