Bond dissociation energy electronegativity effect

The entire set of molecules contained 782 bonds out of which 111 a-bonds were selected. The parameters were calculated by our methods to build a reactivity space with electronegativity difference, resonance effect parameter, bond polarizability, bond polarity, a-charge distribution, and bond dissociation energy as six coordinates. 

Similarly, one may ask how AF110111 would be expected to change in the series C—F, C—Cl, C—Br, and C—I or the series HF, HC1, HBr, and HI. The situation is simpler for these series, since both the electronegativity and orbital size vary but have the same effect on the bond dissociation energy. Variation in orbital size is approximately pro-... 

Nau WM (1997) An electronegativity model for polar ground-state effects on bond dissociation energies. J Phys Oigan Chem 10 445-455... 

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