Bond dissociation energy determination

An alkyl radical and a nitroxide radical exist in an equlibrium with the corresponding alkoxyamine as their coupling product (Eq. 57). Moad and Rizzardo [213] and Kazmaier et al. [214] independently estimated the effects of the structure of the alkyl group and the nitroxide on the dissociation energy of various alkoxyamines into the radicals by semiempirical molecular orbital calculations. The bond dissociation energies determined are summarized in Table 5 ... 

Table 11. Bond dissociation energies determined by electron impact methods. (kJ mol )...

Problem 6.4 without looking at a table of bond dissociation energies, determine which bond in each pair has the higher bond dissociation energy. 

Table 3- Bond dissociation energies determined by Armentrout and coworkers (unless otherwise noted) for meteoric metal oxides and the respective ions.

M-H Bond-dissociation Energies Determined in Solvents other than Acetonitrile... 

H-abstraction reactions of chlorine atoms are often the basis of bond dissociation energy determinations, viz. 

Fig. 2). Using these results a kinetics model based on the Arrhenius equation, in which the activation energy was determined from a fitting a Morse potential using the bond dissociation energy determined from the calculations ... 

Table I. Bond Dissociation Energies Determined from HF Infrared Chemiluminescence. 

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