Bimetallic Organogermanium Derivatives of Groups I, IV and VI Transition Metals

5-1 BIMETALLIC ORGANOGERMANIUM DERIVATIVES OF GROUP I, IV AND VI TRANSITION METALS 

This chapter comprises organogermanes with bonds to silver, gold, titanium, zirconium, chromium, molybdenum and tungsten. The compounds listed in Table 83 are prepared by methods from the following scheme. 

Metathetic substitution with alkali metal salts of transition metal complexes  

By rxn. of Et3GePPh2 with Agl in c.MeCeHxi in inert atm., in 60% yield 

Buff solid, m. 126° (dec.), NMR spectrum, stable as solid in air, slow dec. in refluxing CeHe, soly. (2 4-20). 

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