Biaryl synthesis Negishi coupling

For purposes of completeness, palladium-catalyzed reactions for the synthesis of biaryls using zincates and arylhalides (Negishi Couplings) [254] or using sihcon compounds [255, 256] need to be mentioned. 

In Chapter 1, the authors present a general overview of the classical cross-coupling methods, such as Heck-Mizoroki, Suzuki-Miyaura, Sonogashira, Kumada, Negishi, Ullmann coupling, and modern methods for biaryl unit synthesis, with metals such as Fe and Co. This is a very extensive chapter. 

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