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Benzyne interaction diagram

Figure 11.7. Interaction diagrams comparing (a) ethylene to (b) benzyne. Note that (i I < lAxl-The aromatic n system is largely unperturbed with nearly degenerate orbitals at a — /icc and a + Pcc -... Figure 11.7. Interaction diagrams comparing (a) ethylene to (b) benzyne. Note that (i I < lAxl-The aromatic n system is largely unperturbed with nearly degenerate orbitals at a — /icc and a + Pcc -...
Use orbital interaction diagrams to explain why benzyne is an excellent dienophile in Diels-Alder reactions. [Pg.284]

Diels-Alder reaction, 169-170 aromatic TS, 151 benzyne, 160 butadiene + ethylene, 169 diastereoselectivity, 292 interaction diagram, 169 orbital analysis, 169-170 orbital correlation diagram, 198, 201 reverse demand, 169 substituent effects, 169-170 Diethyl tartrate, 11 Difluorocarbene ( CF2), 115... [Pg.365]

See also in sourсe #XX -- [ Pg.159 ]

See also in sourсe #XX -- [ Pg.159 ]

See also in sourсe #XX -- [ Pg.159 ]

See also in sourсe #XX -- [ Pg.159 ]



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Interaction diagram

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