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1,3,5-Benzenetricarboxylic acid BTC

Supramolecular gels can also be formed using coordination interactions and gels represent a way to control the positioning of metal ions, for example, in nanoparticle synthesis. The reaction of Fe(N03)3 with 1,3,5-benzenetricarboxylic acid (BTC), for example, forms a coordination polymer gel within minutes. There is extensive cross-linking between the Fe and the tricarboxylic acid which leads to voids within the coordination polymer structure (Scheme 5.10). This gel may be used as a polymerisation template. Methyl methacrylate may be polymerised within the gel matrix by UV irradiation of the monomer, resulting... [Pg.280]

Metal organic polymers were used with success in the synthesis of nanometals as well. In one of the reported applications of MOCPs as precursors, calcination in a closed furnace of [Cu3(BTC)J H BTC = 1,3,5-benzenetricarboxylic acid) that include besides compounds decomposition the reduction of the metallic cations determines the formation of coralloid microstructures with surface interspersed comprised of Cu nanoparticle clusters [160]. [Pg.76]

BTC 3,5-benzenetricarboxylate, BDC 1,4-benzenedicarboxylate, THF tetrahydrofuran, mint 2-methybmidazolate, ndc 2,6-naphtalenedicarboxylic acid, ur urotropin, DMF dimethylformamide LSPR localized surface plasmon resonance, IPA isopropyl alcohol... [Pg.174]

See other pages where 1,3,5-Benzenetricarboxylic acid BTC is mentioned: [Pg.74]    [Pg.652]    [Pg.113]    [Pg.2439]    [Pg.1053]    [Pg.390]    [Pg.74]    [Pg.652]    [Pg.113]    [Pg.2439]    [Pg.1053]    [Pg.390]    [Pg.145]    [Pg.108]    [Pg.197]    [Pg.167]    [Pg.2338]    [Pg.234]    [Pg.1037]    [Pg.398]    [Pg.565]    [Pg.95]    [Pg.166]    [Pg.94]   
See also in sourсe #XX -- [ Pg.183 , Pg.280 ]



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1,3,5-benzenetricarboxylate

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