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Benzenesulfenyl chloride 1,4-dienes

Several types of sulfenyl chlorides are known. Sulfur monochloride and dichloride can add to dienes forming sulto bridges. The most commonly used sulfenyl halides are benzenesulfenyl chlorides and methanesulfenyl chloride. Other sulfenyl halides, such as acetylthiosulfenyl chloride and thiocyanogen chloride, have been added to alkenes, but few subsequent transformations have been carried out with those intermediates. ... [Pg.516]

Cyclizations involving sulfenyl chlorides must be designed carefully, since these reagents can also react with alcohols, amines and other nucleophiles. Benzenesulfenyl chloride has been used to cyclize a 1,4-diene. For example, diene (4) cyclizes in good yield to tricyclic heptane product (5). This material was then further elaterated to a cyclosativene precursor (6 equation 4). ... [Pg.517]

See other pages where Benzenesulfenyl chloride 1,4-dienes is mentioned: [Pg.797]    [Pg.152]    [Pg.88]    [Pg.77]   
See also in sourсe #XX -- [ Pg.517 ]

See also in sourсe #XX -- [ Pg.7 , Pg.517 ]

See also in sourсe #XX -- [ Pg.7 , Pg.517 ]

See also in sourсe #XX -- [ Pg.517 ]



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2-Benzenesulfenyl-1,3-dienes

Benzenesulfenyl chloride

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