Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Methyl cation affinity benzene

Methyl cation affinities of benzene and some substituted benzenes have been calculated. These follow a simple additivity rule and the value for benzene shows good agreement with the experimental estimate. Conclusive evidence is presented that these values are linearly related to the corresponding proton affinities. The competition between deuteriation and alkylation in the reaction of radiolytically formed perdeuterio ethyl cations with iV-methylpyrrole and with thiophene has been studied. Deuteriation, the Brpnsted acid pathway, predominates and intramolecular selectivities have been determined for each reaction. ... [Pg.287]

See other pages where Methyl cation affinity benzene is mentioned: [Pg.208]    [Pg.40]    [Pg.192]    [Pg.311]    [Pg.327]    [Pg.277]    [Pg.140]    [Pg.524]    [Pg.1477]    [Pg.1041]    [Pg.348]    [Pg.148]   
See also in sourсe #XX -- [ Pg.287 ]

See also in sourсe #XX -- [ Pg.287 ]

See also in sourсe #XX -- [ Pg.98 , Pg.287 ]



SEARCH



Benzene methyl affinity

Benzene methylation

Methyl affinities

Methyl cation

Methyl cation affinity

© 2024 chempedia.info