Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

BBGKY hierarchy distribution functions

Equation (1.24) is very similar to that of the single-particle distribution function of classical statistical mechanics. In the limit h—>0 we get the first equation of the BBGKY hierarchy. [Pg.184]

Statistical mechanics when based on Liouville s theorem yields a hierarchy of equations (BBGKY hierarchy) that makes use of the 5-particle distribution function /<)< giving the probability of finding s particles, i = 1... j, out of the N particles in the system in the positions ri r, and... [Pg.86]

Equations (4.52) and (4.53) illustrate the BBGKY hierarchy for the equilibrium configurational distribution functions some truncation (closure) is necessary to obtain solutions. For example, neglecting three-body effects by setting cb(ri, rs) = 0, gives from Eq. (4.52) the dilute gas... [Pg.90]

One can proceed by deriving the equation of motion for the two-particle distribution function and so on. Continuing this way, one finds the well-known BBGKY hierarchy, in which distribution functions of higher order enter successively. A detailed study of the two-particle Wigner distribution... [Pg.39]


See other pages where BBGKY hierarchy distribution functions is mentioned: [Pg.476]    [Pg.495]    [Pg.109]    [Pg.451]    [Pg.38]    [Pg.298]    [Pg.207]    [Pg.188]    [Pg.127]    [Pg.204]   
See also in sourсe #XX -- [ Pg.90 ]




SEARCH



Hierarchy

© 2024 chempedia.info