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Base-Catalysed Reactions of Highly Hindered Phenols Used as

Base-Catalysed Reactions of Highly Hindered Phenols Used as Antioxidants [Pg.138]

Deduce the structure of A and give a mechanistic explanation for its formation. [Pg.138]

Oxonine 1, a derivative of the diterpene alkaloid aconitine, undergoes smooth oxidation when treated with exactly one equivalent of periodic acid. The product thus obtained, which shows no aldehyde or ketone absorption in the ir spectrum, is converted into 2 when heated in dilute aqueous base with air passing through the solution. [Pg.138]

Suggest a mechanism for the formation of 2 under these conditions. [Pg.138]




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A-Phenols

Base-catalysed

Base-catalysed reactions

Catalysed reactions

High reactions

Hindered

Hindered phenolics

Hindered phenols

Phenol phenolation reaction

Phenol reactions

Phenolates, reactions

Phenolation reaction

Reactions as Bases

Reactions of Bases

Reactions of Phenols

Use as Bases

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